Efficient and Novel MOF Structured Palladium Catalyst for the Hydrolysis of Dimethylamine Borane
DOI:
https://doi.org/10.5281/zenodo.14566049Keywords:
Pd catalyst, hydrolysis, dimethylamine borane, hydrogenAbstract
In this study, the simple and efficient synthesis of a nanocatalyst with excellent catalytic properties for hydrogen production from the hydrolysis of dimethyl amine-borane (DMAB), one of the hydrogen storage sources, is an incomplete part of the work. In this study, a novel and useful Pd@MOF catalyst was obtained by synthesizing metal organic lattice structure (MOF) and doping Pd metal on it. After the catalyst synthesis conditions were methanolysis of dimethyl amine borane hydrolysis with the synthesized catalyst, the optimum conditions of the hydrogen obtained by methanolysis; different NaOH concentration, catalyst amount and dimethyl amine borane concentration were examined. In addition, methanolysis of dimethyl amine borane in the presence of Pd@MOF catalyst at different temperatures was carried out to determine the activation parameters. It was determined that the reaction degree of the Pd@MOF catalyst was 1st order. At the same time, the hydrolysis of Pd@MOF catalyst in DMAB resulted in a hydrogen production rate of 2036 mL/min*grkat at 30 oC.
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